I know it kind of sounds absurd to ask. All the SO employees would be having this email address ending with stackoverflow dot com. I was just wondering if I can get this address. or does stackoverflow users get this address, may be once they cross a particular reputation mark.
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Rep does not give you a stackoverflow.com email address.
I can imagine that moderators would get one, but don't know for certain.
As the comment by @Fezziwig (?) below and the answer by Simon Sheehan show, moderators do not get their own stackoverflow.com email address either.
Those emails are reserved for Stack Exchange employee. Moderators don't have them; they use their own personal ones, as you mostly see on moderator profiles. This will likely never change: Stack Overflow is a Q&A site, not an email provider.
Server administrators probably have enough on their hands without dealing with your email problems and trying to set up a system for tons of people.