I could really use some advice on my current employment situation (web developer) and whether it is helpful or harmful for me at this point. I'm not sure where I should ask such a question.
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In general, questions that are specific to just you are not really appropriate for the Stack Exchange format. Perhaps you could try finding a local peer group and discussing the question over a beer or other socially acceptable beverage of your choice.
Depends what your question is, but generally career development is on topic on The Workplace. It's not an IT specific site, so keeping your questions generally applicable is a plus, but you can get an impression of what's on topic by browsing the questions and our career development tag.
Expect advice from experts in professional matters not necessarily other programmers, but we have some software industry related questions and users.