Like there is code review site available on Stack Exchange. Is there any site to review css web design?
I want my website to be reviewed from design experts from aesthetic and usability point of view.
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No, there isn't really a website design review site.
Both sites accept answerable questions about specific parts of your design - e.g. "Can I justify using Comic Sans in this kids' flyer?" is given as an example of an OK question in Graphic Design - but general reviews are off topic.
We did have a Design Review site proposal on Area 51, but it has been closed. You could help restart it. See the Announcement of the proposal's closure for more information on that.